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Syllabus 2018-19 - 10312011 - Inorganic Chemistry 2 (Química inorgánica II)

Caption
  • Level 1: Tutorial support sessions, materials and exams in this language
  • Level 2: Tutorial support sessions, materials, exams and seminars in this language
  • Level 3: Tutorial support sessions, materials, exams, seminars and regular lectures in this language
DEGREE: Grado en Químicas
FACULTY: FACULTY OF EXPERIMENTAL SCIENCES

ACADEMIC YEAR: 2018-19
SYLLABUS
1. COURSE BASIC INFORMATION
NAME: Inorganic Chemistry 2
CODE: 10312011 ACADEMIC YEAR: 2018-19
LANGUAGE: English LEVEL: 1
ECTS CREDITS: 6.0 YEAR: 3 SEMESTER: PC
 
2. LECTURER BASIC INFORMATION
NAME: MORENO CARRETERO, MIGUEL NICOLÁS
DEPARTMENT: U128 - QUÍMICA INORGÁNICA Y ORGÁNICA
FIELD OF STUDY: 760 - QUÍMICA INORGÁNICA
OFFICE NO.: B3 - B3-445 E-MAIL: mmoreno@ujaen.es P: 953212738
WEBSITE: http://www4.ujaen.es/~mmoreno/index.htm
LANGUAGE: English LEVEL: 1
 
NAME: JIMÉNEZ PULIDO, SONIA BEATRIZ
DEPARTMENT: U128 - QUÍMICA INORGÁNICA Y ORGÁNICA
FIELD OF STUDY: 760 - QUÍMICA INORGÁNICA
OFFICE NO.: B3 - B3-466 E-MAIL: sjimenez@ujaen.es P: 953212150
WEBSITE: -
LANGUAGE: English LEVEL: 1
 
3. CONTENT DESCRIPTION

0.- INTRODUCTION

Description of the course. Aim and scope, contents and methodology. Bibliography. Assessment.

 

COORDINATION CHEMISTRY

1.- COORDINATION CHEMISTRY BONDING (I): VALENCE BOND AND CRISTAL FIELD THEORIES

Historical background. Valence bond theory: uses, advantages and disadvantages. Crystal field theory. Orbital splitting in octahedral, tetrahedral and square-plane ligand fields. Spectrochemical series. Jahn-Teller's effect. Restrictions of the crystal field theory.

Reading homework: Blomstrand & Jorgensen's chains theory.

 

2.- COORDINATION CHEMISTRY BONDING (II): MOLECULAR ORBITAL THEORY

Experimental covalency evidences of the metal-ligand bond. Molecular orbital theory. Complexes with pi-acceptor and pi-donor ligands.

3.- ELECTRONIC SPECTRA AND MAGNETIC PROPERTIES

Energy levels in the free ions. Racah's parameters. Correlation diagrams: Orgel's and Tanabe-Sugano's plots. Interpretation of the spectra. Magnetic properties. Magneto-structural correlations.

4.- STRUCTURE, STEREOCHEMISTRY AND ISOMERISM

Usual stereochemistries and electronic configuration: Angular overlap model.

Reading homework: Unusual coordination numbers. Non-rigid structrures. Isomerism.

5.- THERMODYNAMIC STABILITY

Stability equilibria and constants. Factors affecting the stability. Chelate, cryptate and macrocyclic effects. Experimental calculation of the stability constants.

Reading homework: Chelate, cryptate and macrocyclic effects.

6.- REACTIONS AND MECHANISMS: SUBSTITUTION AND ELECTRONIC TRANSFER PROCESSES

Substitution reactions in square-plane and octahedral complexes. Associative, dissociative and exchange mechanisms. Trans effect and trans influence. Electron transfer reactions. Outer and inner sphere mechanisms.

Reading homework: Synthetic uses.

7.- INTRODUCTION TO BIOINORGANIC CHEMISTRY

Metals and complexes in biological systems. Oxygen transport and storage. Electron transfer processes. Nitrogen fixation. Pharmacological applications.

Reading homework: Bioinorganic functions.

ORGANOMETALLIC CHEMISTRY 

8.- COMPLEXES WITH PI-ACCEPTOR LIGANDS: METAL CARBONYLS AND NITROSILS

Atomic effective number's rule. Classification of carbonyls. Synthesis and properties. Structure and bond nature. Reactivity. Carbonyl derivatives: carbonylate anions, carbonyl hydrides and halides. Metal nitrosyls: Structure, bond and properties. Complexes with other pi-acceptor ligands.

9.- INTRODUCTION TO ORGANOMETALLIC CHEMISTRY

Introduction. The metal-carbon bond: energy, polarity and reactivity. Factors affecting the stability of the metal-carbon bond. Compounds with sigma and pi metal-carbon bond: Features and kinds of ligands. Pi-olefine compounds. Metallocenes.

10.- ORGANOMETALLIC CHEMISTRY AND CATALYSIS

Homogeneous and heterogeneous catalysis. Organometallics and catalysis.

Reading homework: Examples of homogeneus catalysis.

 

SOLID STATE CHEMISTRY

11.- STRUCTURE OF SOLIDS

Introduction. Crystalline and amorphous solids. Crystal networks. Close-packing based structures. The hard sphere model (HSM). Structure and bond.

12.- DISORDER AND NON-STOICHIOMETRY

Crystal deffects: points and vacants (Schottky) and interstitial (Frenkel). Linear deffects: Edge and helicoidal dislocations. Non-stoichiometric compounds.

13.- SILICATES

Silica: crystal structure and plymorphs. Silicates: Structure. Classification: Single anion, linear, laminar and tridimensional structures.

14.- METALLIC OXIDES

Classification and bond types. Acid-base character. Most common structures. Mixed oxydes: Classification, structure and properties.

15.- ISO AND HETEROPOLYANIONS

Reading homework: Isopolyanions and heteropolyanions structure. General properties.

 

EXPERIMENTAL METHODS FOR STRUCTURAL DETERMINATION OF INORGANIC COMPOUNDS

16.- EXPERIMETAL METHODS FOR STRUCTURAL DETERMINATION OF INORGANIC COMPOUNDS

Spectral methods. Thermal methods. Diffraction methods.

4. COURSE DESCRIPTION AND TEACHING METHODOLOGY

Lecture (Theory): 38 hours

Seminars: 20 hours

Tutorial: 2 hours

Students with special educational needs should contact the Student Attention Service (Servicio de Atención y Ayudas al Estudiante) in order to receive the appropriate academic support

5. ASSESSMENT METHODOLOGY

Exam on the contents of the course (70% theory plus 30% seminars) for every calls.

This is a full evaluation of the reached competences (Q1, Q3, B2, B9, CE6, CE16) from both theoretical and applied points of view.

Warning: In the assessment, errors in basic questions such as formulation, periodic table, electronic configurations, etc., will entail the total annulment of the question.

6. BOOKLIST
MAIN BOOKLIST:
  • Inorganic chemistry. Edition: -. Author: Purcell, Keith F.. Publisher: Philadelphia [etc.]: W. . Saunders, 1977  (Library)
  • Inorganic chemistry. Edition: 4th ed.. Author: Housecroft, Catherine E.. Publisher: New York : Pearson Education, 2012  (Library)
  • Inorganic chemistry. Edition: Fifth edition Gary L. Miessler, St. Olaf College, Paul J. Fischer, Macalester College, Donald A. Tarr, St. Olaf College. Author: Miessler, Gary L., 1949-. Publisher: Harlow : Pearson Education Limited, [2014]  (Library)
  • Descriptive inorganic, coordination, and solid state chemistry. Edition: 3rd ed. Author: Rodgers, Glen E. Publisher: Belmont, CA : Brooks Cole, 2012 [i.e. 2011]  (Library)
  • Basic solid state chemistry. Edition: 2nd ed., repr. Author: West, Anthony R.. Publisher: Chichester [etc.]: John Wiley, 2012  (Library)
  • Shriver & Atkins Inorganic chemistry. Edition: 4th ed. Author: -. Publisher: Oxford: Oxford University Press, 2006  (Library)
ADDITIONAL BOOKLIST:
  • Ligand field theory and its applications. Edition: -. Author: Figgis, Brian N.. Publisher: New York [etc.]: Wiley-VCH, cop. 2000  (Library)
  • Chemistry of the elements. Edition: 2nd ed., repr. Author: Greenwood, N. N.. Publisher: Amsterdam [etc.]: Elsevier : Butterworth Heineman, 2010  (Library)
  • Química inorgánica: principios de estructura y reactividad. Edition: -. Author: Huheey, James E.. Publisher: México: Oxford University Press, cop. 1997  (Library)
  • Chemical Bonding in solids. Edition: -. Author: Burdett, Jeremy K.. Publisher: New York ; Oxford: Oxford University Press, 1995  (Library)
  • Organometallic Chemistry and Catalysis [Recurso electrónico]. Edition: -. Author: Astruc, Didier. Publisher: Berlin, Heidelberg : Springer-Verlag Berlin Heidelberg, 2007.  (Library)
  • Principles of x-ray crystallography. Edition: -. Author: Ooi, Li-ling. Publisher: Oxford : Oxford University Press, 2010  (Library)
  • Structural methods in inorganic chemistry. Edition: 2nd ed. Author: Ebsworth, E. A. V. Publisher: Boca Raton, Fla. : CRC Press, c1991  (Library)
  • Inorganic materials. Edition: 2nd ed., repr. Author: -. Publisher: Chichester [etc.]: John Wiley, 1997  (Library)
  • Symmetry in molecules and crystals. Edition: -. Author: Ladd, M.F.C.. Publisher: Chichester: Ellis Horwood ; New York : Halsted Press, cop. 1989  (Library)