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Syllabus 2017-18 - 10312003 - Instrumental Analytical Chemistry 2 (Química analítica instrumental II)
- Level 1: Tutorial support sessions, materials and exams in this language
- Level 2: Tutorial support sessions, materials, exams and seminars in this language
- Level 3: Tutorial support sessions, materials, exams, seminars and regular lectures in this language
DEGREE: | Grado en Químicas |
FACULTY: | FACULTY OF EXPERIMENTAL SCIENCES |
ACADEMIC YEAR: | 2017-18 |
COURSE: | Instrumental Analytical Chemistry 2 |
NAME: Instrumental Analytical Chemistry 2 | |||||
CODE: 10312003 | ACADEMIC YEAR: 2017-18 | ||||
LANGUAGE: English | LEVEL: 1 | ||||
ECTS CREDITS: 6.0 | YEAR: 3 | SEMESTER: PC |
NAME: GARCÍA REYES, JUAN FRANCISCO | ||
DEPARTMENT: U127 - QUIMÍCA FÍSICA Y ANALÍTICA | ||
FIELD OF STUDY: 750 - QUÍMICA ANALÍTICA | ||
OFFICE NO.: B3 - B3-114 | E-MAIL: jfgreyes@ujaen.es | P: 953213040 |
WEBSITE: http://www4.ujaen.es/~jfgreyes/ | ||
ORCID: https://orcid.org/0000-0001-9158-0271 | ||
LANGUAGE: - | LEVEL: 1 | |
NAME: MORENO GONZALEZ, DAVID | ||
DEPARTMENT: U127 - QUIMÍCA FÍSICA Y ANALÍTICA | ||
FIELD OF STUDY: 750 - QUÍMICA ANALÍTICA | ||
OFFICE NO.: B3 - B-113 | E-MAIL: dmgonzal@ujaen.es | P: 953 212758 |
WEBSITE: http://www10.ujaen.es/conocenos/departamentos/quifis/moreno-gonzalez-david | ||
ORCID: - | ||
LANGUAGE: - | LEVEL: 1 |
THEORY
Lesson 1. Introduction
Introduction to trace analysis. Separation techniques in trace analysis. Classification of separation techniques
Lesson 2. Introduction and theory of chromatography. 1.Definitions and classification of chromatographic techniques. Fundamentals and key parameters in chromatography. N, H, resolution, efficiency,ââââ¬Å¡¬¦ Effect of mobile phase flow rate. Van Deemter equation. Applications. Qualitative and quantitative analysis
Lesson 3. Gas chromatography. 1. Introduction. Classification of GC methods. Instrumentation. Gas. Column. Inyection system. Stationary phases. Temperature in GC. Detectors. GC-GC and GCxGC. Applications.
Lesson 4. Liquid chromatography. 1. Introduction. Instrumentation in HPLC. Pumps. Injection system. Columns. Stationary phases. Chiral chromatography. Mobile phases. Detectors in HPLC. Working modes in HPLC. Effect of temperatura in HPLC. Ultra-high pressure liquid chromatography (UHPLC). LCxLC. Microflow and nanoflow LC. Applications.
Lesson 5. Ion chromatography. Fundamentals of ion chromatography. Stationary phases. Mobile phases. Detection. Ion Suppressor.
Lesson 6. Size exclusion, planar and supercritical fluid chromatography. Size exclusion chromatography. Thin-layer chromatography. Supercritical fluid chromatography
Lesson 7. Capillary Electrophoresis and capillary electrochromatography. 1. Introduction. Basics of capillary electrophoresis. Migration phenomena. Electrophoretic mobility and electroosmotic flow. Instrumentation in capillary electrophoresis. Sample introduction. Detecton. CE modes. Capillary Zone electrophoresis. Micellar electrokinetic chromatography. Isotacophoresis. Isoelectric focusing. Capillary gel electrophoresis. Capillary electrochromatography. Analytical applications.
Lesson 8. Sample treatment for trace analysis. Introduction to sample treatment. Liquid-liquid extraction. Solid-phase extraction (SPE). Solid-phase microextraction (SPME). Stir bar sorptive extraction (SBSE). Headspace (HS). Matrix solid-phase dispersión (MSPD). Soxhlet extraction. Pressurized liquid extraction. Supercritical fluid extraction
Lesson 9. Introduction to mass spectrometry. 1- Instrumentation. Ionization in MS. Electron Impact. Chemical Ionization. Electrospray. APCI. MALDI. Analyzers. Tandem mass spectrometry. Fragmentaiton. High resolution mass spectrometry. Basic of mass spectra interpretation
Lesson 10. Hyphenated techniques I: GC-MS and LC-MS. 1. Instrumentation.2. Applications
Lesson 11: Elemental mass spectrometry and speciation. ICP-MS: Fundamentals and applications. Hyphenation of ICP-MS and chromatography. Speciation analysis and its applications
Lesson 12. Automation. Introduction. Flow methods. Flow inyection analysis. Sequential injection analysis. Applications
LABORATORY SESSIONS
- Selected questions and use of HPLC simulator
- Analytical applications of HPLC
- Analytical applications of GC
Theoretical classes (38 hours). Lecture notes and material provided in platform or upon request to Professor.
Laboratory sessions (10 hours). A lab report template (hand-out) will be provided.
Seminars (10 hours). 5 sessions (2h) with different practical tasks to accomplish associated to the theoretical contents.
Students with special educational needs should contact the Student Attention Service (Servicio de Atención y Ayudas al Estudiante) in order to receive the appropriate academic support
Theoretical exam (70 %).
Laboratory session and preparation of lab report (15 %)
Seminars and tasks: presentation of a topic agreed with tutor (15 %)
- Extraction techniques in analytical sciences. Edition: -. Author: Dean, John A. (John Aurie). Publisher: Chichester, West Sussex, U.K. ; Hoboken, NJ : J. Wiley, 2009. (Library)
- The essence of chromatography. Edition: -. Author: Poole, Colin F.. Publisher: Amsterdam: Elsevier, 2003 (Library)